| dc.contributor.author | Lee, Hong Geun | |
| dc.contributor.author | Milner, Phillip John | |
| dc.contributor.author | Colvin, Michael Thomas | |
| dc.contributor.author | Andreas, Loren | |
| dc.contributor.author | Buchwald, Stephen Leffler | |
| dc.date.accessioned | 2016-11-21T18:47:26Z | |
| dc.date.available | 2016-11-21T18:47:26Z | |
| dc.date.issued | 2014-06 | |
| dc.date.submitted | 2014-05 | |
| dc.identifier.issn | 00201693 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/105383 | |
| dc.description.abstract | The structure of the stable Pd(0) precatalyst [(1,5-cyclooctadiene)(L•Pd)[subscript 2]] (L = AdBrettPhos) for the Pd-catalyzed fluorination of aryl triflates has been further studied by solid state NMR and Xray cystrallography of the analogous N-phenylmaleimide complex. The reactivity of this complex with CDCl[subscript 3] to form a dearomatized complex is also presented. In addition, studies suggest that related bulky biaryl phosphine ligands form similar complexes, although the smaller ligand BrettPhos forms a monomeric [(1,5-cyclooctadiene)(L•Pd)] species instead. | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (Grants GM46059, EB003151, EB001960 and EB002026) | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (Pre-Doctoral Fellowship) | en_US |
| dc.description.sponsorship | Amgen Inc. | en_US |
| dc.language.iso | en_US | |
| dc.publisher | Elsevier | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1016/j.ica.2014.06.008 | en_US |
| dc.rights | Creative Commons Attribution-NonCommercial-NoDerivs License | en_US |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | en_US |
| dc.source | PMC | en_US |
| dc.title | Structure and reactivity of [(L·Pd)[subscript n]·(1,5-cyclooctadiene)] (n=1–2) complexes bearing biaryl phosphine ligands | en_US |
| dc.title.alternative | Structure and reactivity of [(L·Pd)n·(1,5-cyclooctadiene)] (n=1–2) complexes bearing biaryl phosphine ligands | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Lee, Hong Geun et al. “Structure and Reactivity of [(L·Pd)n·(1,5-Cyclooctadiene)] (n=1–2) Complexes Bearing Biaryl Phosphine Ligands.” Inorganica Chimica Acta 422 (2014): 188–192. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Lee, Hong Geun | |
| dc.contributor.mitauthor | Milner, Phillip John | |
| dc.contributor.mitauthor | Colvin, Michael Thomas | |
| dc.contributor.mitauthor | Andreas, Loren | |
| dc.contributor.mitauthor | Buchwald, Stephen Leffler | |
| dc.relation.journal | Inorganica Chimica Acta | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Lee, Hong Geun; Milner, Phillip J.; Colvin, Michael T.; Andreas, Loren; Buchwald, Stephen L. | en_US |
| dspace.embargo.terms | N | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0001-8075-1100 | |
| dc.identifier.orcid | https://orcid.org/0000-0003-0710-0429 | |
| dc.identifier.orcid | https://orcid.org/0000-0003-3875-4775 | |
| mit.license | PUBLISHER_CC | en_US |
