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Structures of oxalate oxidoreductase : C₂ activation by a microbial TPP-dependent ferredoxin oxidoreductase
(Massachusetts Institute of Technology, 2015)
Oxalic acid is a two-carbon diprotic acid that is toxic to humans. In large doses, it can cause death by poisoning, and in smaller doses over time it can lead to chronic renal disease, such as the formation of kidney stones, ...
Biomimetic carboxylate-bridged diiron complexes : from solution behavior to modeling the secondary coordination sphere
(Massachusetts Institute of Technology, 2015)
Chapter 1: Understanding the Utility of Hydrogen Bonding Donors in the Secondary Coordination Sphere of Non-heme Metal Complexes Chapter 1 is a mini-review that covers systematic studies on the effect of hydrogen bonding ...
The reactivity and cation exchange of MOF-5
(Massachusetts Institute of Technology, 2015)
The aim of this thesis is to demonstrate that the inorganic clusters within MOF-5 can be derivatized with redox-active cations for subsequent use in coordination chemistry and small-molecule activation. Rather than reproduce ...
Exploring reactivity and component interactions in Toluene/o-Xylene Monooxygenase from pseudomonas sp. OX1
(Massachusetts Institute of Technology, 2015)
Chapter 1. Component Interactions in Three- and Four-Component Bacterial Multicomponent Monooxygenases. Bacterial multicomponent monooxygenases (BMMs) catalyze oxidation of hydrocarbon substrates through activation of ...