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An experimental study of OH uptake by surfaces of tropospheric importance under dry and wet conditions
(Massachusetts Institute of Technology, 2008)
The effect of relative humidity (RH) on OH uptake by surfaces of tropospheric importance was investigated. Due to diffusion limitation conditions, experiments were performed with parallel reactors packed with beads and ...
Syntheses and studies of group 6 terminal pnictides, early-metal trimetaphosphate complexes, and a new bis-enamide ligand
(Massachusetts Institute of Technology, 2011)
Investigated herein is the reactivity of the terminal-nitrido, trisanilide tungsten complex, NW(N[i- Pr]Ar)3 (Ar = 3,5-Me 2C6H3, 1). Nitride 1 has been shown to undergo an "N for (O)C1 metathesis with a variety of acid ...
Synthesis, characterization and reactivity of organometallic Zr(IV) carboxylate and titanium aminotroponiminate complexes
(Massachusetts Institute of Technology, 1999)
The synthesis and structure of several Zr(IV) carboxylate complexes are described in which the bridging carboxylate is the dianion of 111-xylylenediamine bis(Kemp's triacid imide) (H2XDK) or the more soluble propyl derivative ...
Spectroscopic investigations of the X and A state dynamics of ¹³C₂H₂
(Massachusetts Institute of Technology, 2002)
The objective of the experiments described in this thesis is to perform a detailed spectroscopic study of the dynamics on the A and X state surfaces of 13C2H2 in order to further understand the acetylene - vinylidene ...
Complexation, coupling, and cleavage of organonitriles, alkynes, dinitrogen, hydrostannanes or phosphines by three-coordinate molybdenum(III) complexes
(Massachusetts Institute of Technology, 2002)
The biosynthetic Claisen condensation : mechanistic enzymology of biosynthetic thiolase from Zoogloea ramigera
(Massachusetts Institute of Technology, 1987)
Numerical simulations in nuclear magnetic resonance : theory and applications
(Massachusetts Institute of Technology, 2003)
Exact numerical simulations of NMR experiments are commonly required for the engineering of new techniques and for the extraction of structural and dynamic parameters from the spectra. The calculations can be very demanding, ...
Photodetectors based on colloidal quantum dots
(Massachusetts Institute of Technology, 2007)
Inspired by recent work demonstrating photocurrent enhancement in quantum-dot (QD) solids via post-deposition chemical annealing and by recent successes incorporating single monolayers of QDs in light-emitting devices ...
Organoboranes in organic synthesis
(Massachusetts Institute of Technology, 1989)
The total synthesis of carbohydrates
(Massachusetts Institute of Technology, 1987)