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Two-electron mixed-valence complexes small molecule activation and photocatalytic hydrogen production
(Massachusetts Institute of Technology, 2001)
Two-electron mixed-valence complexes of rhodium may be supported by diphosphazane ligands (RN(PY2)2). Whereas diphosphazane ligands with strongly [pi]-acidic phosphine groups (Y = F, OCH2CF3) react with RhI starting materials ...