Isotopic constraints on the sources and associations of organic compounds in marine sediments
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71196529-MIT.pdf
Description
Full printable version
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18.8 MB
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ae47c7e72e1b84fbe5fe7a23b63e6898
Author(s)
White, Helen K
Advisor(s)
Christopher M. Reddy.
Date Issued
2006
Publisher
Massachusetts Institute of Technology
Abstract
To provide a new perspective on the fate of both natural organic matter and hydrophobic organic contaminants (HOCs) in marine sediments, we have investigated the relationship between radiocarbon (14C) age and the different modes of association in aquatic sediments and soils. Radiocarbon is a sensitive tracer of OM provenance, with variations in its natural abundance reflecting the age and origin of material. The main objective has been to determine the significance of these associations, and to assess how they affect the transport, bioavailability, preservation and residence times of organic compounds in the environment. Our results indicate that the majority of HOCs that persist in marine sediments are solvent-extractable and incorporation into insoluble sediment residues is not quantitatively significant. For pristine sediments, systematic variations in 14C content are observed between different chemically defined sedimentary organic fractions. These variations are dependent on organic matter inputs and/or the affects of diagenesis. Our observations also provide evidence for the protection of labile marine carbon by chemical binding.
(cont.) Finally, the persistence of n-alkanes from biogenic sources compared to those derived from petroleum indicates that protective matrix association can play a crucial role in determining the long-term fate of a compound. Overall, it is clear that both natural organic compounds and HOCs can undergo very different fates depending on their mode of introduction to, and physical disposition in environmental matrices.
Description
Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2006.
Includes bibliographical references.
Subjects
Joint Program in Oceanography.
Earth, Atmospheric, and Planetary Sciences.
Woods Hole Oceanographic Institution.
MIT Department
Joint Program in Oceanography
Woods Hole Oceanographic Institution
Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences
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