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Understanding the Induced Self-Assembly System Between PEO-b-PAA and Iron

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dc.contributor.author Sondjaja, H. Ronny
dc.contributor.author Tam, Michael K.C.
dc.contributor.author Yap, Miranda G.S.
dc.contributor.author Hatton, T. Alan
dc.date.accessioned 2007-02-06T01:10:00Z
dc.date.available 2007-02-06T01:10:00Z
dc.date.issued 2007-01
dc.identifier.uri http://hdl.handle.net/1721.1/35879
dc.description.abstract The induced self-assembly phenomenon between PEO-b-PAA and Fe(II) was investigated. It was revealed that the electrostatic interaction between Fe(II) in the form of green rust (GR²⁺) particles and the COO- groups from the PAA backbone at pH 7 causes the formation of stable aggregates with Dh~156 nm. While it is stable at pH 7, the induced self-assembly structure, however, is disordered during the transformation of GR²⁺ into Fe₃O₄. The pH increment and the oxidation process itself were found to affect the stability. en
dc.description.provenance Submitted by Matthew Mahoney (mahoney1@mit.edu) on 2007-02-01T19:45:39Z No. of bitstreams: 1 CPE014.pdf: 10468 bytes, checksum: df8d272a7717293370969208505f8643 (MD5) en
dc.description.provenance Approved for entry into archive by Robert Wolfe(rwolfe@mit.edu) on 2007-02-06T01:10:00Z (GMT) No. of bitstreams: 1 CPE014.pdf: 10468 bytes, checksum: df8d272a7717293370969208505f8643 (MD5) en
dc.description.provenance Made available in DSpace on 2007-02-06T01:10:00Z (GMT). No. of bitstreams: 1 CPE014.pdf: 10468 bytes, checksum: df8d272a7717293370969208505f8643 (MD5) Previous issue date: 2007-01 en
dc.description.sponsorship Singapore-MIT Alliance (SMA) en
dc.language.iso en en
dc.relation.ispartofseries Chemical and Pharmaceutical Engineering (CPE) en
dc.subject PEO-b-PAA en
dc.subject Self-Assembly en
dc.title Understanding the Induced Self-Assembly System Between PEO-b-PAA and Iron en
dc.type Article en

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