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Radical synthesis of trialkyl, triaryl, trisilyl and tristannyl phosphines from P₄

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Radical synthesis of trialkyl, triaryl, trisilyl and tristannyl phosphines from P₄

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Author: Cossairt, Brandi M.; Cummins, Christopher C.
Department: Massachusetts Institute of Technology. Dept. of Chemistry
Publisher: RSC Publishing
Date Issued: 2010-04
Abstract:
A reaction scheme has been devised according to 3 RX + 3 Ti(III) + 0.25 P₄ → PR₃ + 3 XTi(IV), wherein RX = PhBr, CyBr, Me₃SiI or Ph₃SnCl, with contrasting results in the case of more hindered RX. The scheme accomplishes the direct radical functionalization of white phosphorus without the intermediacy of PCl₃.
URI: http://hdl.handle.net/1721.1/67661
ISSN: 1144-0546
Citation: Cossairt, Brandi M., and Christopher C. Cummins. “Radical Synthesis of Trialkyl, Triaryl, Trisilyl and Tristannyl Phosphines from P4.” New Journal of Chemistry 34.8 (2010) : 1533.
Version: Author's final manuscript
Terms of Use: Creative Commons Attribution-Noncommercial-Share Alike 3.0
Detailed Terms: http://creativecommons.org/licenses/by-nc-sa/3.0/
Published As: http://dx.doi.org/10.1039/c0nj00124d
Journal: New Journal of Chemistry

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