| dc.contributor.author | Tonzetich, Zachary J. | |
| dc.contributor.author | Heroguel, Florent | |
| dc.contributor.author | Do, Loi Hung | |
| dc.contributor.author | Lippard, Stephen J. | |
| dc.date.accessioned | 2012-02-10T15:47:17Z | |
| dc.date.available | 2012-02-10T15:47:17Z | |
| dc.date.issued | 2011-01 | |
| dc.date.submitted | 2010-11 | |
| dc.identifier.issn | 0020-1669 | |
| dc.identifier.issn | 1520-510X | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/69074 | |
| dc.description.abstract | Several nitrosyl complexes of Fe and Co have been prepared using the sterically hindered Ar-nacnac ligand (Ar-nacnac = anion of [(2,6-diisopropylphenyl)NC(Me)]2CH). The dinitrosyliron complexes [Fe(NO)2(Ar-nacnac)] (1) and (Bu4N)[Fe(NO)2(Ar-nacnac)] (2) react with [FeIII(TPP)Cl] (TPP = tetraphenylporphine dianion) to generate [FeII(NO)(TPP)] and the corresponding mononitrosyliron complexes. The factors governing NO transfer with dinitrosyliron complexes (DNICs) 1 and 2 are evaluated, together with the chemistry of the related mononitrosyliron complex, [Fe(NO)Br(Ar-nacnac)] (4). The synthesis and properties of the related cobalt dinitrosyl [Co(NO)2(Ar-nacnac)] (3) is also discussed for comparison to DNICs 1 and 2. The solid-state structures of several of these compounds as determined by X-ray crystallography are reported. | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (grant CHE-0907905) | en_US |
| dc.description.sponsorship | National Institute of General Medical Sciences (U.S.) (postdoctoral fellowship, F32 GM082031-03) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ic102300d | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | Prof. Lippard via Erja Kajosalo | en_US |
| dc.title | Chemistry of Nitrosyliron Complexes Supported by a beta-Diketiminate Ligand | en_US |
| dc.title.alternative | Chemistry of Nitrosyliron Complexes Supported by a β-Diketiminate Ligand | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Tonzetich, Zachary J. et al. “Chemistry of Nitrosyliron Complexes Supported by a β-Diketiminate Ligand.” Inorganic Chemistry 50.4 (2011): 1570-1579. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.approver | Lippard, Stephen J. | |
| dc.contributor.mitauthor | Lippard, Stephen J. | |
| dc.contributor.mitauthor | Tonzetich, Zachary J. | |
| dc.contributor.mitauthor | Heroguel, Florent | |
| dc.contributor.mitauthor | Do, Loi Hung | |
| dc.relation.journal | Inorganic Chemistry | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Tonzetich, Zachary J.; Héroguel, Florent; Do, Loi H.; Lippard, Stephen J. | en |
| dc.identifier.orcid | https://orcid.org/0000-0002-2693-4982 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
