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A New Class of Nonionic Photosensitive Surfactants: Some Insights Concerning Conformations

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dc.contributor.author Smith, Kenneth A.
dc.contributor.author Hatton, T. Alan
dc.contributor.author Shang, Tiangang
dc.contributor.author Cicciarelli, Brad
dc.date.accessioned 2004-12-15T23:54:28Z
dc.date.available 2004-12-15T23:54:28Z
dc.date.issued 2005-01
dc.identifier.uri http://hdl.handle.net/1721.1/7486
dc.description.abstract We report on a new class of nonionic, photosensitive surfactants consisting of a polar di(ethylene oxide) head group attached to an alkyl spacer of between two and eight methylene groups, coupled through an ether linkage to an azobenzene moiety. Structural changes associated with the interconversion of the azobenzene group between its cis and trans forms as mediated by the wavelength of an irradiating light source cause changes in the surface tension and self-assembly properties. Differences in saturated surface tensions (surface tension at concentrations above the CMC) were as high as 14.4 mN/m under radiation of different wavelengths. The qualitative behavior of the surfactants changed as the spacer length changed, attributed to the different orientations adopted by the different surfactants depending on their isomerization states, as revealed by neutron reflection studies. The self-assembly of these photosensitive surfactants has been investigated by light scattering, small angle neutron scattering, and cryo-TEM under different illuminations. The significant change in the self-assembly in response to different illumination conditions was attributed to the sign change in Gaussian rigidity, which originated from the azobenzene photoisomerization. en
dc.description.sponsorship Singapore-MIT Alliance (SMA) en
dc.format.extent 1484258 bytes
dc.format.mimetype application/pdf
dc.language.iso en
dc.relation.ispartofseries Molecular Engineering of Biological and Chemical Systems (MEBCS);
dc.subject azobenzene en
dc.subject photosensitive surfactants en
dc.subject surface tension en
dc.title A New Class of Nonionic Photosensitive Surfactants: Some Insights Concerning Conformations en
dc.type Article en


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