Browsing Chemistry - Ph.D. / Sc.D. by Title
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Browsing Chemistry - Ph.D. / Sc.D. by Title
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(Massachusetts Institute of Technology, 1994)
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Engineered heme peroxidases as genetically encoded probes with diverse applications in cell biology (Massachusetts Institute of Technology, 2015)Proteins perform myriad functions inside cells. In vitro studies of purified proteins yield important information about their function, but it is an important pursuit in cell biology to study proteins within the native ...
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(Massachusetts Institute of Technology, 2013)Major impediments to the full utility of current and potential drugs include issues of resistance and delivery. To address these challenges, in this thesis two directions of research were pursued: (1) the use of multivalent ...
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(Massachusetts Institute of Technology, 2012)This thesis explores the use of ensemble, free energy models in the study and design of molecular, biochemical systems. We use physics based computational models to analyze the molecular basis of binding affinity in the ...
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(Massachusetts Institute of Technology, 2013)Each eukaryotic cell is exquisitely divided into organellar compartments whose functions are uniquely defined by the set of proteins they possess. For each individual protein, precise targeting to a specific sub-cellular ...
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Enzyme engineering by directed evolution and applications in cellular imaging and proteomic mapping (Massachusetts Institute of Technology, 2016)A thorough understanding of biological systems on a molecular level requires tools to study individual protein components within the native cellular context. A wide panoply of enzyme-mediated labeling methodologies have ...
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Enzyme-mediated labeling of proteins and protein-protein interactions in vitro and in living cells (Massachusetts Institute of Technology, 2010)The E. coli biotin ligase enzyme, BirA, has been previously used by the Ting research group for site-specific labeling of peptide-tagged cell surface proteins. We sought to expand the utility of biotin ligase-mediated ...
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(Massachusetts Institute of Technology, 2016)The neuronal synapse is one of the most important cellular structures in neuroscience. It is the junction through which signaling occurs between neurons that in aggregate, mediates complex physiological brain function. At ...
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(Massachusetts Institute of Technology, 1979)
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2010)Chapter 1: Reaction of Mo(NR)(CHR')(OTf)2(dme) (R = 2,6-i-Pr2C6H3 (Ar), 2,6-Me2C6H3 (Ar'), 2,6-Cl2C6H3 (ArCl), 1-adamantyl (Ad); R' = CMe2Ph, CMe3; dme = dimethoxyethane) with the lithium salt of ArCl-nacnac ([2,6-Cl2C6H ...
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(Massachusetts Institute of Technology, 2012)Our understanding of organic materials for solar energy conversion stands to benefit greatly from accurate, computationally tractable electronic structure methods for excited states. Here we apply two approaches based on ...
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Exciton-polaritons in thermal equilibrium : from Bose-Einstein condensation to exciton-polaritonics (Massachusetts Institute of Technology, 2017)Coherent control has been at the heart of the study of physical chemistry. Great advancement has been achieved in the past few decades in coherent control of classical systems by using spatially and temporally shaped ...
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(Massachusetts Institute of Technology, 2006)Chapter 1. The first detailed study of the palladium-catalyzed amination of aryl nonaflates is reported. Use of bulky electron-rich monophosphinobiaryl ligands or BINAP allow for the catalytic amination of electron-rich ...
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(Massachusetts Institute of Technology, 2004)Three principal analytical methods: circular dichroism (CD), hydrogen exchange, and the t/c ratio of Ac-Hel, a helix stabilizing N-cap, are used in combination to quantify fractional helicity in order to determine the ...
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(Massachusetts Institute of Technology, 1999)
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(Massachusetts Institute of Technology, 1994)
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2008)The effect of relative humidity (RH) on OH uptake by surfaces of tropospheric importance was investigated. Due to diffusion limitation conditions, experiments were performed with parallel reactors packed with beads and ...
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(Massachusetts Institute of Technology, 2010)Plant alkaloid biosynthesis produces many natural products with medicinal value. For example, vinblastine and vincristine from Catharanthus roseus monoterpene indole alkaloid biosynthesis, and camptothecin derivatives from ...
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