Browsing Chemistry - Ph.D. / Sc.D. by Title
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Browsing Chemistry - Ph.D. / Sc.D. by Title
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(Massachusetts Institute of Technology, 2003)In this thesis, the chemistry of sulfur oxides on transition metals is studied extensively via first-principles density functional theory (DFT) computations, focusing on the chemical reactivity and selectivity in sulfur ...
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(Massachusetts Institute of Technology, 2004)Chapter 1. Fluorescence-Based Detection Methodologies for Nitric Oxide: A Review. Chapter 2. Cobalt Chemistry with Mixed Aminotroponimine Salicylaldimine Ligands: Synthesis, Characterization, and Nitric Oxide Reactivity. ...
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(Massachusetts Institute of Technology, 2006)Chapter 1. An Introduction to Zinc Metalloneurochemistry and Zinc Detection in Biology. This chapter presents an overview of zinc neurophysiology and pathology, which provides motivation for the design of new tools and ...
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(Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 2013)The niobium-phosphorus triple bond in [P=-Nb(N[Np]Ar)3]- (Np = CH2tBu; Ar = 3,5-Me2C6H3) has produced the first case of P4 activation by a metal-ligand multiple bond. Treatment of P4 with the sodium salt of the niobium ...
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(Massachusetts Institute of Technology, 1994)
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 2012)Carbon nanotubes (CNTs) possess a unique set of electrical and mechanical properties and have been used in a variety of applications. In this thesis, we explore strategies to functionalize CNTs as well as applications which ...
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(Massachusetts Institute of Technology, 1987)
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(Massachusetts Institute of Technology, 1943)
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(Massachusetts Institute of Technology, 2006)Advances in our understanding of cellular function and signal transduction have resulted in ever increasing number of therapeutical targets and, consequently, underscored a demand for simple and universally applicable ...
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(Massachusetts Institute of Technology, 2006)The reaction matrix of multichannel quantum defect theory, K, gives a complete picture of the electronic structure and the electron - nuclear dynamics for a molecule. The reaction matrix can be used to examine both bound ...
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(Massachusetts Institute of Technology, 2009)In this thesis research, I implemented a terahertz generation scheme that enables high-field near-single-cycle terahertz (THz) pulse generation via optical rectification in a LiNbO3 (LN) crystal. I also developed a method ...
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(Massachusetts Institute of Technology, 2005)A discussion of the anomalous low-temperature thermal properties of amorphous materials is first given as a theoretical framework in which the rest of the thesis is treated. The theory models the form and function of ...
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(Massachusetts Institute of Technology, 2006)The radicals nitric oxide and superoxide are produced endogenously by activated macrophages and neutrophils and combine in a diffusion-limited reaction to form peroxynitrite, a powerful oxidizing and nitrating agent capable ...
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(Massachusetts Institute of Technology, 2005)Poly(phenylene-ethynylene) (PPE), a fully conjugated polymer system, exhibits high solution state quantum yields, narrow emission profiles, and wide band gaps allowing for blue emission, making them ideal candidates for ...
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(Massachusetts Institute of Technology, 1999)
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(Massachusetts Institute of Technology, 2012)Multi-electron reaction chemistry, from both ground- and excited-state species, is at the heart of many topics in renewable energy and catalysis. In this thesis, two classes of reactions central to the themes of energy ...
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(Massachusetts Institute of Technology, 2011)Building blocks, containing majority fluorine content by weight, for PPEs and PPVs have been synthesized. Some of the monomers were shown to give exclusively fluorous-phase soluble polymers, the syntheses of which were ...
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(Massachusetts Institute of Technology, 2014)Solid State Nuclear Magnetic Resonance (ssNMR) spectroscopy has blossomed over the last two decades. As ssNMR is progressively applied to more challenging systems, the sensitivity remains one of its major limiting factors. ...
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