Browsing Chemistry - Ph.D. / Sc.D. by Title
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Browsing Chemistry - Ph.D. / Sc.D. by Title
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(Massachusetts Institute of Technology, 1994)
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(Massachusetts Institute of Technology, 2005)A general amination strategy for the N-alkynylation of carbamates, sulfonamides, and chiral oxazolidinones and imidazolidinones is described. A variety of substituted ynamides are available by deprotonation of amide ...
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(Massachusetts Institute of Technology, 2006)Colloidal semiconductor nanocrystals (NCs) or quantum dots (QDs) can be synthesized to efficiently emit light from the ultraviolet, across the entire visible spectrum, and into the near infrared. This is now possible due ...
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(Massachusetts Institute of Technology, 2006)The attempted syntheses of molybdenum imido alkylidene complexes of the type Mo(NArc,)(CH-t-Bu)[Biphen] and Mo(N-2-CF3C6H4)(CHCMe2Ph)[Biphen] (Biphen2 = 3,3'-di-t-butyl-5,5',6,6'-tetramethyl- 1,1'-biphenyl-2,2'-diolate) ...
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(Massachusetts Institute of Technology, 1993)
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 1995)
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Synthesis of nitrogen heterocycles via the intramolecular [4+2] cycloaddition of iminoacetonitriles (Massachusetts Institute of Technology, 2003)Iminoacetonitriles have been shown to function as aza dienophiles in intramolecular Diels-Alder reactions, affording substituted quinolizidines and indolizidines. The cycloadducts are formed with a high preference for an ...
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(Massachusetts Institute of Technology, 1951)
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Synthesis of polycyclic furans via the generation and rearrangement of strained heterocyclic allenes (Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 2006)This dissertation describes studies of the feasibility and scope of intramolecular [4+2] cycloadditions of hetarenynes and alkynes as a method for the synthesis of polycyclic benzo[b]-fused five-membered heteroaromatic ...
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(Massachusetts Institute of Technology, 1962)
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(Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 1984)
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(Massachusetts Institute of Technology, 1984)
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(Massachusetts Institute of Technology, 2005)A series of pure iron jarosites (formula AFe₃(OH)₆(TO₄)₂) possessing the paradigmatic kagomé lattice has been prepared stoichiometrically pure through the use of a redox-based hydlrothermal synthetic strategy. This synthetic ...
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(Massachusetts Institute of Technology, 2008)Stoichiometrically pure S = 1/2 Cu2+ kagomé materials have been synthesized. Such materials provide an ideal venue for exploration of quantum states on a kagomé because they exhibit strong geometric spin frustration and ...
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(Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 2006)This thesis presents the synthesis, structure and reactivity of two-coordinate Group 11 metal complexes, supported by N-heterocyclic carbene (NHC) ligands. The NHC ligand was found to stabilize monomeric, terminal fluoride ...
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