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Browsing Department of Chemistry by Title
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(Massachusetts Institute of Technology, 2010)Chapter 1: A highly active catalyst system based upon a biaryl monophosphine ligand, XPhos, for the palladium-catalyzed Stille reaction has been developed. This method allows for the coupling of aryl chlorides with a range ...
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 1986)
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(Massachusetts Institute of Technology, 1993)
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(Massachusetts Institute of Technology, 2011)Amyloid fibrils are insoluble, non-crystalline protein filaments associated with a number of diseases such as Alzheimer's and Type Il diabetes. They can have a functional role in different organisms and many proteins and ...
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(Massachusetts Institute of Technology, 1958)
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(Massachusetts Institute of Technology, 2016)Herein three systems - electromigration in metal nanowires, electron tunneling in single-molecules, and carbon nanotube photovoltaics - are investigated. In the first area, electromigrative failure of metal nanowires has ...
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(Massachusetts Institute of Technology, 2004)Highly convergent annulation strategies have been developed for the synthesis of azulenes and polycyclic nitrogen heterocycles. Specifically, substituted azulenes have been synthesized via a ring expansion-annulation ...
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(Massachusetts Institute of Technology, 2013)Viruses are a major cause of human morbidity and mortality in the world. New effective approaches to stop their spread are paramount. Herein, two approaches toward this goal are explored: (i) developing multivalent ...
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(Massachusetts Institute of Technology, 2002)Our research over the last four years has been focused on the development of mild and general methods for conducting palladium-catalyzed carbon-carbon bond forming reactions utilizing the bulky and electron-rich ...
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(Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 1999)
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(Massachusetts Institute of Technology, 2017)This thesis is about the study and application of a stochastic optimization algorithm - Random Matrix Theory coupled with Neural Networks (RMT-RNN) to large static systems with relatively large disorder in mesoscopic ...
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Application of sensitive spectroscopic techniques to intramolecular dynamics and combustion kinetics (Massachusetts Institute of Technology, 2002)Modifications of Cavity Ringdown Spectroscopy (CRD) for use in the UV region are discussed. These modifications partially overcome the low sensitivity of CRD in the UV (due to lower mirror reflectivity, R - 0.99) by removal ...
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 2002)Based on a strategy developed in our group for the desymmetrization of planar heterocycles, we have designed, synthesized, and resolved a number of bidentate, C2-symmetric planar-chiral bis(azaferrocenes) that bear a ...
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