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Browsing Department of Chemistry by Title
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(Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 1999)
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(Massachusetts Institute of Technology, 2005)Inhibition of the chaperone protein Hsp90 in plants and insects has been found to result in drastic changes in phenotype. We investigated the effect of Hsp90 inhibition on the bacteria Streptomyces coelicolor. These changes ...
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(Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 2004)Class II major histocompatibility complex (MHC) proteins bind peptides and present them at the cell surface for interaction with CD4+ T cells as part of the system by which the immune system surveys the body for signs of ...
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(Massachusetts Institute of Technology, 2002)The interaction of low energy XeF2 with Si(100)2x1 has been investigated by studying both the surface-bound and gas-phase products of the reaction. Helium atom diffraction, beam-surface scattering and thermal desorption ...
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(Massachusetts Institute of Technology, 1997)
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Interactions of light with matter-- applications to single molecule spectroscopy and quantum control (Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 1999)
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(Massachusetts Institute of Technology, 2001)The triplet electronic states of acetylene and the intersystem crossing process that populates these states were studied using a second-generation, supersonic jet molecular beam machine with a multispectral capability. ...
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2008)Seven- and eight-membered carbocycles are key features in numerous naturally occurring organic substances, many of which are biologically important natural products. This thesis describes studies directed towards the ...
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(Massachusetts Institute of Technology, 2002)The intramolecular [4 + 2] cycloaddition reactions of c,-alkynyl carbonyl compounds are described. This reaction, the first heterocyclic variant of the enyne cycloaddition reaction, affords a product with a dihydroisobenzofuran ...
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(Massachusetts Institute of Technology, 1996)
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Intramolecular Heck couplings of unactivated alkyl electrophiles : synthetic and mechanistic studies (Massachusetts Institute of Technology, 2007)A method for the palladium-catalyzed intramolecular Heck coupling of unactivated alkyl bromides and chlorides is described. The optimal catalyst system was composed of Pd2(MeO-dba)3 as the metal source and N-heterocyclic ...
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Investigating asparagine-linked glycosylation substrate : specificity and effects on protein folding (Massachusetts Institute of Technology, 2009)N-linked glycosylation is a ubiquitous form of protein modification whereby a preassembled oligosaccharide is covalently attached the asparagine side chain of an acceptor protein. This process involves numerous enzymes, ...
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(Massachusetts Institute of Technology, 2006)N-linked protein glycosylation is characterized by the formation of a -glycosylamine linkage to an asparagine residue within the Asn-Xaa-Ser/Thr consensus sequence. This modification is found in organisms from eukaryotic, ...
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(Massachusetts Institute of Technology, 2010)The optical measurements described in this thesis reveal interactions among bound electron-hole pairs known as excitons in a semiconductor nanostructure. Excitons are quasiparticles that can form when light is absorbed by ...
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(Massachusetts Institute of Technology, 2006)The biosynthesis of asparagine-linked glycoproteins, highly conserved throughout all eukaryotes, requires a dolichylpyrophosphate-linked tetradecasaccharide precursor (Dol-PP-GlcNAc2Man9Glc3), from which the tetradecasaccharide ...
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