Browsing Department of Chemistry by Title
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Browsing Department of Chemistry by Title
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(Massachusetts Institute of Technology, 2005)This thesis contains the foundational work behind the field of polaritonics. Corresponding to a frequency range from roughly 100 gigahertz up to 10 terahertz, polaritonics bridges the gap between electronics and photonics. ...
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(Massachusetts Institute of Technology, 2006)Dynamic Nuclear Polarization (DNP) is utilized to enhance NMR signal intensities in systems including metals, ceramics, polymers and biological solids. The enhancement results from polarization transfers from unpaired ...
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 2009)Ion channels are essential mediators in nervous signaling pathways. Because hyperactivation of ion channels can lead to pathological disorders such as congenital myasthenic syndromes and neurodegeneration, channel inhibitors ...
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(Massachusetts Institute of Technology, 2008)This thesis details the development of new synthetic methods for making polymers with complex molecular structures. Calix[4]arenes and triptycenes are the two major molecular building blocks for constructing the functional ...
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(Massachusetts Institute of Technology, 2006)The incorporation of molecular structures such as shape persistent molecular frameworks, strong hydrogen bond donor groups or perfluoro-alkyl groups can result in considerable gains in the performance of some established ...
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 2005)Conjugated polymers have shown remarkable sensitivity for the detection of a variety of analytes, ranging from explosives to biological molecules such as DNA. This thesis presents three new applications of poly(phenylene ...
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(Massachusetts Institute of Technology, 2011)Polyisoprenyl-dependent glycan assembly pathways form the basis for the biosynthesis of many complex glycoconjugates. This thesis addresses key aspects of undecaprenyl-phosphate related processes; undecaprenol is the linear ...
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(Massachusetts Institute of Technology, 2006)In preparation for performing a triple resonance experiment to study the Rydberg states of calcium monofluoride (CaF), a double resonance spectrum of formaldehyde will be recorded. A dye laser will populate a level in ...
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(Massachusetts Institute of Technology, 1939)
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(Massachusetts Institute of Technology, 1936)
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(Massachusetts Institute of Technology, 1988)
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(Massachusetts Institute of Technology, 1936)
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 1940)
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(Massachusetts Institute of Technology, 2009)Chapter 1 describes the development of two organocatalytic processes. The first is a 13-alkylation reaction of Michael acceptors, and represents a novel umpolung process catalyzed by N-heterocyclic carbenes. The second ...
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(Massachusetts Institute of Technology, 2008)In Chapter 1, the first enantioselective cross-coupling reactions of racemic secondary benzylic halides are described (eq 1). This method was applied to the syntheses of intermediates employed by other groups in the ...
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(Massachusetts Institute of Technology, 2012)A tandem benzannulation-cyclization strategy was successfully applied to the synthesis of a tetracyclic heteroaromatic compound expected to have interesting electronic properties. Benzannulation of a diazo ketone and a ...
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