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Browsing Department of Chemistry by Title
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(Massachusetts Institute of Technology, 1936)
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(Massachusetts Institute of Technology, 1988)
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(Massachusetts Institute of Technology, 1936)
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 1940)
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(Massachusetts Institute of Technology, 2009)Chapter 1 describes the development of two organocatalytic processes. The first is a 13-alkylation reaction of Michael acceptors, and represents a novel umpolung process catalyzed by N-heterocyclic carbenes. The second ...
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(Massachusetts Institute of Technology, 2008)In Chapter 1, the first enantioselective cross-coupling reactions of racemic secondary benzylic halides are described (eq 1). This method was applied to the syntheses of intermediates employed by other groups in the ...
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(Massachusetts Institute of Technology, 2012)A tandem benzannulation-cyclization strategy was successfully applied to the synthesis of a tetracyclic heteroaromatic compound expected to have interesting electronic properties. Benzannulation of a diazo ketone and a ...
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(Massachusetts Institute of Technology, 1982)
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(Massachusetts Institute of Technology, 1990)
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(Massachusetts Institute of Technology, 1994)
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(Massachusetts Institute of Technology, 2010)Methodological developments and applications of solid-state magic-angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy, with particular emphasis on the analysis of protein structure, are described in this thesis. ...
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2007)Proton-coupled electron transfer (PCET) is the basic mechanism for bioenergetic conversion. Hallmark examples of such reactivities include water oxidation which is coupled to photosynthesis and oxygen reduction which is ...
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(Massachusetts Institute of Technology, 2004)Ribonucleotide reductases (RNRs) comprise a biologically indispensable enzyme class which converts the four common nucleotides to their corresponding deoxynucleotides via a thiyl radical hydrogen abstraction mechanism. As ...
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(Massachusetts Institute of Technology, 1960)
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(Massachusetts Institute of Technology, 2010)Terpene indole alkaloids (TIAs) are a class of natural products produced in plants. Many TIAs have medicinal uses; for example, vinblastine has anti-cancer activity and ajmaline has anti-arrhythmic activity. Many TIAs did ...
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(Massachusetts Institute of Technology, 2005)Excessive fat synthesis and the subsequent dysregulation of lipid metabolism constitute the major pathological factors of obesity and type 2 diabetes through triggering insulin resistance. Thus, controlling fat synthesis ...
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(Massachusetts Institute of Technology, 2007)Three special topics in the field of molecular spectroscopy are investigated using a variety of computational techniques. First, large-amplitude vibrational motions on ground-state singlet (S0) potential energy surfaces ...
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