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Browsing Department of Chemistry by Title
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(Massachusetts Institute of Technology, 2005)Chapter 1: The capability of Mo(N[t-BulAr)₃ to act as a powerful one, two, and three electron reductant have been previously demonstrated. In this work, we show that Mo(NIt-BulAr)₃ forms a metastable adduct with the moderate ...
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 2010)The concentration of transition metals within the cell must be tightly regulated. If the concentration of a given transition metal is too low the cell may not be able to perform life-sustaining processes, while high levels ...
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(Massachusetts Institute of Technology, 1935)
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 1994)
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(Massachusetts Institute of Technology, 2011)The medicinal plant Madagascar periwinkle (Catharanthus roseus) produces over 130 monoterpene indole alkaloid (MIA) natural products. Many of these compounds have pharmaceutical value, such as the anticancer agents vinblastine ...
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(Massachusetts Institute of Technology, 1999)
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2008)To study the nucleotide reduction system in Archaea, we have expressed the Archaeoglobus fulgidus gene encoding the adenosylcobalamin (AdoCbl) dependent ribonucleotide reductase (afuRNR) protein. Initial characterization ...
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2012)The highly cis,head-to-tail (cis,HT) selective ring-opening metathesis polymerization of 3-substituted cyclooctenes (3-RCOE; R = methyl, hexyl, phenyl) initiated by high oxidation state M and W alkylidene complexes is ...
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(Massachusetts Institute of Technology, 1994)
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(Massachusetts Institute of Technology, 2008)Defects and fluctuations dominate both static and dynamical properties of systems in the condensed phase. In this work, we focus on three such examples. Firstly, we model the effect of proton fluctuations on the rate of ...
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(Massachusetts Institute of Technology, 2002)Cisplatin (cis-diamminedichloroplatinum(ll)) is a successful DNA-damaging anticancer drug used in the treatment of testicular, ovarian and other tumors. In the past decade, several mutually non-exclusive hypotheses have ...
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(Massachusetts Institute of Technology, 2007)This thesis summarizes progress toward the ultimate goal of building a complete structural and dynamical model for the CaF molecule. The quantum defects of the Rydberg series of the molecule, as well as their dependences ...
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 2004)Considered to be a prototype for e⁻ <--> nuclear interaction in more complex molecules, the Alkaline earth monohalides (MX) have a simple electronic structure which consists of two closed-shell atomic ions (M²⁺ + X) in the ...
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