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Browsing Department of Chemistry by Title
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(Massachusetts Institute of Technology, 1992)
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(Massachusetts Institute of Technology, 2003)Glycosaminoglycans are crucial components of the extracellular matrix and cell surface and access to define sequences is required to fully appreciate their role in biology. As is the case with most complex polysaccharides, ...
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(Massachusetts Institute of Technology, 2005)Light-driven energy conversion schemes have been proposed as alternative energy to fossil fuels. The target fuel of these schemes is hydrogen. For photocatalytic hydrogen production to be feasible, it must be performed on ...
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2012)This work describes a phenomenological approach for modeling linear and nonlinear infrared spectroscopy of condensed phase chemical systems, focusing on applications to strongly hydrogen bonded complexes. To overcome the ...
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(Massachusetts Institute of Technology, 2009)Human dietary exposure to aflatoxin B1 (AFB1) is linked to hepatocellular carcinoma (HCC), especially in areas where significant hepatitis B infection is concurrent. Susceptibility to this carcinogen varies among species. ...
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(Massachusetts Institute of Technology, 1997)cis-Diamminedichloroplatinum(II) (cis-DDP or cisplatin) is a powerful cytotoxin and anticancer therapeutic, used most effectively in the treatment of testicular and ovarian cancers. By contrast, the geometric isomer of ...
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(Massachusetts Institute of Technology, 2001)Chapter 1. The asymmetric Pauson-Khand cyclization of nitrogen-containing enynes using carbon monoxide and a catalytic amount of (EBTHI)TiMe2 was examined. The influence of the nitrogen substituent and the concentration ...
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(Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 2008)Energy-dependent proteases, such as the E. coli protease ClpAP, degrade misfolded and short-lived regulatory proteins inside the cell. In this class of proteins, an ATPase component (e.g., ClpA) binds, unfolds, and ...
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(Massachusetts Institute of Technology, 2002)Chapter 1. Triptycenes are shown to possess "internal free volume" swept out between their aromatic faces, which enable them to align their long axis normal to the host alignment to most efficiently fill this volume. This ...
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(Massachusetts Institute of Technology, 2009)A series of monomeric copper complexes that allow for the tuning of the emission properties is reported. Luminescence lifetimes up to 150 [mu]s are observed in benzene solution at ambient temperature, which are comparable ...
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(Massachusetts Institute of Technology, 2010)Chapter 1. Investigating the Biological Roles of Nitric Oxide and Other Reactive Nitrogen Species Using Fluorescent Probes: This chapter presents an overview of recent progress in the field of reactive nitrogen species ...
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Two-dimensional polymer synthesis : towards a two-dimensional replicating system for nanostructures (Massachusetts Institute of Technology, 2005)The general concept of a replicating monolayer system is introduced as a new method of nanostructure synthesis. One possible implementation of a 2-D replicating system is pursued which uses a diacetylene moiety for ...
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(Massachusetts Institute of Technology, 2005)This thesis develops powerful new methods for shaping femtosecond laser pulses in two dimensions and explores their application to coherent control of propagating lattice excitations and degenerate four-wave mixing ...
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(Massachusetts Institute of Technology, 2001)Two-electron mixed-valence complexes of rhodium may be supported by diphosphazane ligands (RN(PY2)2). Whereas diphosphazane ligands with strongly [pi]-acidic phosphine groups (Y = F, OCH2CF3) react with RhI starting materials ...
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2009)Cofactors assist enzymes with a variety of complex chemistries. Two versatile cofactors, flavin adenine dinucleotide (FAD) and non-heme iron, together with molecular oxygen as an oxidizing agent, perform a wide array of ...
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(Massachusetts Institute of Technology, 2008)The experimental measurement technique of ultrafast dynamic ellipsometry (UDE) was developed for measuring material motion and changes in optical properties of samples under laser driven shock loading. Ultrafast dynamic ...
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(Massachusetts Institute of Technology, 1990)
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