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Browsing Theses - Chemistry by Title
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(Massachusetts Institute of Technology, 1999)
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(Massachusetts Institute of Technology, 2008)Nitric oxide (NO) is a molecule that is essential for life and regulates both beneficial and harmful processes. Because this gaseous radical influences many aspects of health and disease, we wish to explore the relationship ...
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(Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 1988)
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(Massachusetts Institute of Technology, 1914)
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Development and application of chemical tools for investigating dynamic processes in cell migration (Massachusetts Institute of Technology, 2011)Cell migration is a dynamic process essential for many fundamental physiological functions, including wound repair and the immune response. Migration relies on precisely orchestrated events that are regulated in a spatially ...
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(Massachusetts Institute of Technology, 2005)Chapter 1. Copper-Catalyzed Arylation of Stabilized Carbanions A mild, general catalytic system for the synthesis of [alpha]-aryl malonates has been developed. Aryl iodides bearing a variety of functional groups can be ...
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(Massachusetts Institute of Technology, 1999)
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(Massachusetts Institute of Technology, 2004)Chapter 1. PALLADIUM-CATALYZED REGIOSELECTIVE HYDRODEBROMINATION OF DIBROMOINDOLES A novel approach to the selective preparation of 4-bromoindoles has been developed via a Pd-catalyzed reaction. A variety of 4,6-dibromoindoles, ...
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(Massachusetts Institute of Technology, 2011)Chapter 1 A procedure for forming a highly active Pd(0) catalyst from Pd(OAc) 2, water, and biarylphosphine ligands has been developed. This protocol generates a catalyst system, which exhibits excellent reactivity and ...
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 2009)Chapter 1. Ti-Catalyzed Asymmetric Reduction of Aromatic Heterocycles A method for the highly selective asymmetric reduction of quinoxalines and quinazolines was developed. This complements technologies developed by others ...
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(Massachusetts Institute of Technology, 2007)A direct two-step method for the preparation of 2-aryl- and 2-vinyl-4-quinolones that utilizes a copper-catalyzed amidation of ortho-halophenones followed by a base-promoted Camps cyclization of the resulting N-(2-keto-aryl)amides ...
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(Massachusetts Institute of Technology, 1999)
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(Massachusetts Institute of Technology, 2012)Semiconductor nanocrystals, also known as quantum dots (QDs), are promising imaging probes with characteristic optical properties: tunable bandgap from visible to infrared, narrow and symmetric emission features, broad ...
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(Massachusetts Institute of Technology, 2005)I. The Development of Methods for the Iterative Synthesis of Polytetrahydropyrans An iterative method comprising chain homologation, epoxidation, 6-endo cyclization, and protiodesilylation was developed. Notable achievements ...
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(Massachusetts Institute of Technology, 2008)To determine the function of proteins of interest, chemical biologists employ their full panoply of techniques, including X-ray crystallography and NMR spectroscopy for structural information, and luminescence spectroscopy ...
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 2005)Nuclear magnetic resonance (NMR) spectroscopy is unique in the content of structural as well as dynamic information that it can provide at atomic resolution. The aim of this PhD-thesis was to contribute to the understanding ...
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(Massachusetts Institute of Technology, 2008)I. The Development of a General Strategy Towards Dimeric Hexahydropyrroloindole Alkaloids. A Concise Total Synthesis of (+)-Chimonanthine, (+)-Folicanthine and (-)Calycanthine. An efficient and convergent strategy for the ...
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