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Browsing Theses - Chemistry by Title
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(Massachusetts Institute of Technology, 1992)
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(Massachusetts Institute of Technology, 2008)Metal-catalyzed nucleophilic substitution reactions of aryl halides have become one of the most valuable and useful classes of reactions developed in the last 30 years. Foremost among these processes are the classes of ...
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(Massachusetts Institute of Technology, 2008)Chapter 1. Highly active and efficient catalyst systems derived from palladium precatalysts and monophosphine ligands for the Suzuki-Miyaura cross-coupling reaction of heteroaryl boronic acids and esters has been developed. ...
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 2005)Chapter 1: The capability of Mo(N[t-BulAr)₃ to act as a powerful one, two, and three electron reductant have been previously demonstrated. In this work, we show that Mo(NIt-BulAr)₃ forms a metastable adduct with the moderate ...
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 2010)The concentration of transition metals within the cell must be tightly regulated. If the concentration of a given transition metal is too low the cell may not be able to perform life-sustaining processes, while high levels ...
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(Massachusetts Institute of Technology, 1935)
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 1994)
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(Massachusetts Institute of Technology, 2011)The medicinal plant Madagascar periwinkle (Catharanthus roseus) produces over 130 monoterpene indole alkaloid (MIA) natural products. Many of these compounds have pharmaceutical value, such as the anticancer agents vinblastine ...
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(Massachusetts Institute of Technology, 1999)
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2008)To study the nucleotide reduction system in Archaea, we have expressed the Archaeoglobus fulgidus gene encoding the adenosylcobalamin (AdoCbl) dependent ribonucleotide reductase (afuRNR) protein. Initial characterization ...
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2012)The highly cis,head-to-tail (cis,HT) selective ring-opening metathesis polymerization of 3-substituted cyclooctenes (3-RCOE; R = methyl, hexyl, phenyl) initiated by high oxidation state M and W alkylidene complexes is ...
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(Massachusetts Institute of Technology, 1994)
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(Massachusetts Institute of Technology, 2008)Defects and fluctuations dominate both static and dynamical properties of systems in the condensed phase. In this work, we focus on three such examples. Firstly, we model the effect of proton fluctuations on the rate of ...
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