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Browsing Theses - Chemistry by Title
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(Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 2011)The vanadium nitride complex [Na][NV(N['Bu]Ar) 3] reacts with CO to produce the vanadium tris-anilide complex V(N['Bu]Ar)3 and NaNCO. This is the first example of complete denitrogenation of a termainal nitride complex ...
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(Massachusetts Institute of Technology, 2006)The E. coli Very Short Patch Repair (VSPR) system corrects T:G mismatches that arise through Dcm-mediated methylation and subsequent deamination of the underlined cytosine residue in the palindromic sequence 5'-CCWGG-3' ...
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(Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 1989)
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(Massachusetts Institute of Technology, 2006)The utilization of biological factors in the design, synthesis and fabrication of nano-scaled materials and devices presents novel, large scale solutions for the realization of future technologies. In particular, we have ...
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(Massachusetts Institute of Technology, 2004)Theory and methods to design ligands with enhanced binding affinity and specificity for use as biological therapeutics were developed. These methods involve electrostatic charge optimization techniques and packing ...
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(Massachusetts Institute of Technology, 1987)
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(Massachusetts Institute of Technology, 2004)Porous anodic alumina (PAA) films were utilized to template the fabrication of nanostructures of bismuth, antimony and bismuth-antimony alloys. The cylindrical template pores were used to synthesize nanowires by electrochemical ...
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 2005)Within cellular signaling, protein phosphorylation is the post-translational modification most frequently used to regulate protein activity. Protein kinases and phosphoprotein phosphatases generate and terminate these ...
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(Massachusetts Institute of Technology, 2007)Protein phosphorylation is a central regulatory mechanism in signal transduction pathways and cellular migration. Current genetic strategies for the study of phosphorylation, including gene knockout and point mutation, are ...
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(Massachusetts Institute of Technology, 2009)Isothermal titration calorimetry (ITC) was developed as a technique for qualitatively comparing the heat of absorption of small molecules to single-walled carbon nanotubes (SWCNTs). In agreement with other studies, it was ...
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(Massachusetts Institute of Technology, 2004)The intermolecular, three-component carbonyl ylide cycloaddition of a diazo compound, aldehyde, and carbon-carbon multiple bond is a powerful method to construct five-membered oxygen heterocycles. An adjacent dicobalt ...
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(Massachusetts Institute of Technology, 1994)
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(Massachusetts Institute of Technology, 1999)
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 2007)This thesis presents a study of the reaction between an (NHC)gold(I) fluoride complex (NHC = N-heterocyclic carbene) and alkynes (Chapter 1). Gold(I) and fluoride add trans across the triple bond of 3-hexyne and ...
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(Massachusetts Institute of Technology, 2004)In Part I the development of a new method for the construction of oxindoles and benzofuranones bearing quaternary stereocenters is discussed. A planar-chiral PPY derivative catalyzes the O-to-C acyl group migration (Black ...
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(Massachusetts Institute of Technology, 1995)
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