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Browsing Theses - Chemistry by Title
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(Massachusetts Institute of Technology, 2012)Multi-electron reaction chemistry, from both ground- and excited-state species, is at the heart of many topics in renewable energy and catalysis. In this thesis, two classes of reactions central to the themes of energy ...
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(Massachusetts Institute of Technology, 1912)
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(Massachusetts Institute of Technology, 2011)Building blocks, containing majority fluorine content by weight, for PPEs and PPVs have been synthesized. Some of the monomers were shown to give exclusively fluorous-phase soluble polymers, the syntheses of which were ...
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2004)There are numerous advantages to high frequency (high field) electron paramagnetic resonance (EPR) spectroscopy. Two of the most important are improved sensitivity and the improved resolution of field dependent interactions. ...
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(Massachusetts Institute of Technology, 2004)Enantiomerically pure molybdenum imido alkylidene complexes of the type Mo(NAr)(CHCMe₂Ph)[Ar'](THF), which contained 3,3'-diaryl (Ar' = Mes (21), Ph (22)) substituted binaphtholate ligands, were prepared and structurally ...
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(Massachusetts Institute of Technology, 2011)Dynamic Nuclear Polarization (DNP) has exploded in popularity over the last few years, finally realizing its potential to overcome the detrimental lack of sensitivity that has plagued performing NMR experiments. Applied ...
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(Massachusetts Institute of Technology, 1972)
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(Massachusetts Institute of Technology, 2005)The occurrence of certain alkaloids in the human brain appears to be associated with the onset of Parkinson's disease (PD). Recently, a human protein bearing homology to an alkaloid synthase in plants was identified. This ...
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(Massachusetts Institute of Technology, 2004)Hydrogen bonding between N-methylacetamide (NMA) and different solvents (D₂O or CDCl₃) was studied by using two-dimensional infrared spectroscopy to probe the frequency fluctuations of the amide I mode of the solvated NMA. ...
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(Massachusetts Institute of Technology, 2010)Compared with other molecular liquids, water is highly structured due to its ability to form up to four hydrogen bonds to its nearest neighbors, resulting in a tetrahedral network of molecules. However, this network is ...
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(Massachusetts Institute of Technology, 2011)Water consists of an extended hydrogen bond network that is constantly evolving. More than just a description of the time averaged structure is necessary to understand any process that occurs in water. In this thesis we ...
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(Massachusetts Institute of Technology, 1940)
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(Massachusetts Institute of Technology, 1977)
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(Massachusetts Institute of Technology, 1994)
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2007)The development of an improved synthesis of nucleophilic planar-chiral catalysts is described in Chapter 1. This route is amenable to scale-up and preparative chiral HPLC is unnecessary to resolve the racemic catalysts. ...
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(Massachusetts Institute of Technology, 2009)Chapter 1. An Introduction to Fluorescent Zn(II) Sensors and Their Applications in Biological Systems This chapter opens with an overview of the numerous roles of zinc in biology, with an emphasis on labile Zn(II), that ...
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(Massachusetts Institute of Technology, 1996)
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