Browsing Chemistry - Master's degree by Title
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Browsing Chemistry - Master's degree by Title
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(Massachusetts Institute of Technology, 2007)A direct two-step method for the preparation of 2-aryl- and 2-vinyl-4-quinolones that utilizes a copper-catalyzed amidation of ortho-halophenones followed by a base-promoted Camps cyclization of the resulting N-(2-keto-aryl)amides ...
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 1974)
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(Massachusetts Institute of Technology, 2006)Molybdenum complexes ... were used to synthesize polyene oligomeric compounds with up to 15 conjugated double bonds by reaction with aldehyde compounds in a Wittig-like fashion. The optical properties of highly nr-conjugated ...
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(Massachusetts Institute of Technology, 2008)solid State NMR (SSNMR) can determine molecular as well as supermolecular structure and dynamics. The low signal intensities make many of these experiments prohibitively long. Dynamic Nuclear Polarization provides a method ...
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 2004)Chapter 1: Complexes obtained by electrophilic attack on a dinitrogen-derived terminal molybdenum nitride: Electronic structure analysis by solid state CP/MAS ¹⁵N NMR in combination ... Chapter 2. Carbene chemistry in the ...
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(Massachusetts Institute of Technology, 2012)A method for the nickel-catalyzed cross-coupling between benzoxazole and secondary halides was explored. This method was to make use of the activated C-H bond found in benzoxazole at the 2-position to generate the nucleophilic ...
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(Massachusetts Institute of Technology, 2007)Caseinolytic protease A (ClpA), a member of the Hsp 100 family of heat shock proteins, is the regulatory subunit of the E. coli protease ClpAP. As such, it recognizes proteins targeted for degradation by the cell and uses ...
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(Massachusetts Institute of Technology, 2010)Despite being a seemingly simple molecule, acetylene has a complicated electronic structure that has been studied extensively both experimentally and theoretically. Acetylene has been observed to have a complex spin-orbit ...
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(Massachusetts Institute of Technology, 2011)Introduction: Complete understanding of the mechanisms of biological processes, indispensable for the rational design and testing of therapeutic strategies, can be greatly facilitated by easy and rapid access to macromolecular ...
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(Massachusetts Institute of Technology, 2013)In this thesis, we present experimental methods and results of tabletop generation of high power single-cycle and frequency-tunable multiple-cycle terahertz (THz) pulses pumped with near-infrared ultrashort optical pulses ...
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2004)Hydrogen bonding between N-methylacetamide (NMA) and different solvents (D₂O or CDCl₃) was studied by using two-dimensional infrared spectroscopy to probe the frequency fluctuations of the amide I mode of the solvated NMA. ...
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(Massachusetts Institute of Technology, 1977)
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(Massachusetts Institute of Technology, 2008)Seven- and eight-membered carbocycles are key features in numerous naturally occurring organic substances, many of which are biologically important natural products. This thesis describes studies directed towards the ...
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Intramolecular Heck couplings of unactivated alkyl electrophiles : synthetic and mechanistic studies (Massachusetts Institute of Technology, 2007)A method for the palladium-catalyzed intramolecular Heck coupling of unactivated alkyl bromides and chlorides is described. The optimal catalyst system was composed of Pd2(MeO-dba)3 as the metal source and N-heterocyclic ...
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Investigation of freezing properties of polar statospheric cloud particles with optical microscopy (Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 2011)Hydrophobic polycations have been shown to completely kill bacterial, fungal, and viral pathogens, on-contact. Herein we describe advances with this technology on two fronts: (1) innovation of a polycationic-derivative ...
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(Massachusetts Institute of Technology, 1995)
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