Browsing Chemistry - Master's degree by Title
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Browsing Chemistry - Master's degree by Title
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2004)Hydrogen bonding between N-methylacetamide (NMA) and different solvents (D₂O or CDCl₃) was studied by using two-dimensional infrared spectroscopy to probe the frequency fluctuations of the amide I mode of the solvated NMA. ...
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(Massachusetts Institute of Technology, 1977)
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(Massachusetts Institute of Technology, 2008)Seven- and eight-membered carbocycles are key features in numerous naturally occurring organic substances, many of which are biologically important natural products. This thesis describes studies directed towards the ...
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Intramolecular Heck couplings of unactivated alkyl electrophiles : synthetic and mechanistic studies (Massachusetts Institute of Technology, 2007)A method for the palladium-catalyzed intramolecular Heck coupling of unactivated alkyl bromides and chlorides is described. The optimal catalyst system was composed of Pd2(MeO-dba)3 as the metal source and N-heterocyclic ...
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Investigation of freezing properties of polar statospheric cloud particles with optical microscopy (Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 2011)Hydrophobic polycations have been shown to completely kill bacterial, fungal, and viral pathogens, on-contact. Herein we describe advances with this technology on two fronts: (1) innovation of a polycationic-derivative ...
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 2004)Chapter 1: The Importance of Modeling Diiron Sites in Nature.There are a variety of metalloenzymes that have nearly identical carboxylate-bridged diiron active sites. An example is sMMOH, an enzyme that catalyzes the ...
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(Massachusetts Institute of Technology, 2009)The palladium-catalyzed cross-coupling of aryl bromides with zirconocene-benzyne complexes has been investigated by S.L. Buchwald and coworkers. This method allows the formation of substituted biphenyls and terphenyls, ...
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(Massachusetts Institute of Technology, 2005)Precatalyst species present in a solution of Pd₂(dba)₃ and Xantphos were identified as Pd(Xantphos)(dba) and Pd(Xantphos)₂ by use of ³¹p NMR and independent syntheses. Pd(Xantphos)₂ was found to form at high ligand ...
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 1995)
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2007)Catalytic Asymmetric Reductive Coupling of 1,3-Enynes and Aromatic Aldehydes Nickel-catalyzed reductive coupling reactions of 1,3-enynes and aromatic aldehydes efficiently afford conjugated dienols in excellent regioselectivity ...
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(Massachusetts Institute of Technology, 2012)A recently developed bis-pyridinylidene neutral organic electron donor captured our interest as a potential source of new chemistries for reductive coupling and the synthesis of group IV nanoparticles. This super electron ...
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(Massachusetts Institute of Technology, 2003)
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(Massachusetts Institute of Technology, 2007)Photoluminescent energy transfer in conjugated polymer-dye blend films was studied by means of steady-state fluorescence spectroscopy in order to identify efficient energy acceptors with red-shifted emissions relative to ...
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(Massachusetts Institute of Technology, 1994)
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(Massachusetts Institute of Technology, 1992)
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