Discovery of the Seven-ring Polycyclic Aromatic Hydrocarbon Cyanocoronene (C24H11CN) in GOTHAM Observations of TMC-1
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Wenzel_2025_ApJL_984_L36.pdf
Description
Published version
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1.93 MB
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Checksum (MD5)
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Author(s)
Wenzel, Gabi
Gong, Siyuan
Xue, Ci
Changala, P Bryan
Holdren, Martin S
Speak, Thomas H
Stewart, D Archie
Fried, Zachary TP
Willis, Reace HJ
Bergin, Edwin A
Date Issued
April 30, 2025
Journal
The Astrophysical Journal Letters
Publisher
American Astronomical Society
Citation
Gabi Wenzel et al 2025 ApJL 984 L36
Version
Final published version
Abstract
We present the synthesis and laboratory rotational spectroscopy of the seven-ring polycyclic aromatic hydrocarbon (PAH) cyanocoronene (C24H11CN) using a laser-ablation-assisted cavity enhanced Fourier transform microwave spectrometer. A total of 71 transitions were measured and assigned between 6.8 and 10.6 GHz. Using these assignments, we searched for emission from cyanocoronene in the Green Bank Telescope (GBT) Observations of TMC-1: Hunting Aromatic Molecules project observations of the cold dark molecular cloud TMC-1 using the100 m GBT. We detect a number of individually resolved transitions in ultrasensitive X-band observations and perform a Markov Chain Monte Carlo analysis to derive best-fit parameters, including a total column density of N ( C24H11 CN) = +2.69-0.23 x 1012 cm-2 at a temperature of 6.05+0.38-0.37 K. A spectral stacking and matched filtering analysis provides a robust 17.3σ significance to the overall detection. The derived column density is comparable to that of cyano-substituted naphthalene, acenaphthylene, and pyrene, defying the trend of decreasing abundance with increasing molecular size and complexity found for carbon chains. We discuss the implications of the detection for our understanding of interstellar PAH chemistry and highlight major open questions and next steps.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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DOI of Published Version
https://doi.org/10.3847/2041-8213/adc911
