Synthesis of a BDPA-TEMPO Biradical
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Swager_Synthesis of with supporting doc.pdf
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Author(s)
Dane, Eric L.
Maly, Thorsten
Debelouchina, Galia Tzvetanova
Griffin, Robert Guy
Swager, Timothy M
Date Issued
March 2009
Journal
Organic Letters
Publisher
American Chemical Society
Citation
Dane, Eric L. et al. “Synthesis of a BDPA-TEMPO Biradical.” Organic Letters 11.9 (2009): 1871–1874. Web.
Version
Author's final manuscript
Abstract
The synthesis and characterization of a biradical containing a 1,3-bisdiphenylene-2-phenylallyl (BDPA) free radical covalently attached to a 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) free radical are described. The synthesis of the biradical is a step toward improved polarizing agents for dynamic nuclear polarization (DNP).
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology)
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DOI of Published Version
https://doi.org/10.1021/ol9001575
