Enhanced durability of carbon nanotube grafted hierarchical ceramic microfiber-reinforced epoxy composites
Name
Enhanced durability of carbon nanotube grafted hierarchical ceramic microfiber-reinforced epoxy composites_final version.pdf
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2.02 MB
Format
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Checksum (MD5)
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Author(s)
Krishnamurthy, Ajay
Hunston, Donald L.
Forster, Amanda L.
Natarajan, Bharath
Liotta, Andrew H.
Wicks, Sunny S.
Stutzman, Paul E.
Wardle, Brian L.
Liddle, J. Alexander
Forster, Aaron M.
Date Issued
September 17, 2017
Journal
Carbon
Publisher
Elsevier
Citation
Krishnamurthy, Ajay, et al. “Enhanced Durability of Carbon Nanotube Grafted Hierarchical Ceramic Microfiber-Reinforced Epoxy Composites.” Carbon 125 (December 2017): 63–75.
Version
Author's final manuscript
Abstract
Carbon nanotube (CNT) hierarchical composites are increasingly identified as next-generation aerospace materials, so it is vital to evaluate their long-term structural performance under aging environments. In this work, the durability of hierarchical CNT grafted aluminoborosilicate microfiber-epoxy composites (CNT composites) are compared against aluminoborosilicate composites (baseline composites), before and after immersion in water at 25 °C (hydro) and 60 °C (hydrothermal), for extended durations (90 d and 180 d). The addition of CNTs is found to reduce water diffusivities by approximately 1.5 times. The mechanical properties (bending strength and modulus) and the damage sensing capabilities (DC conductivity) of the CNT composites remain intact regardless of exposure conditions. The baseline composites show significant loss of strength (44%) after only 15 d of hydrothermal aging. This loss of mechanical strength is attributed to fiber-polymer interfacial debonding caused by accumulation of water at elevated temperatures. In situ acoustic and DC electrical measurements of hydrothermally aged CNT composites identify extensive stress-relieving micro-cracking and crack deflections that are absent in the aged baseline composites. SEM images of the failed composite cross-sections highlight secondary matrix toughening mechanisms in the form of CNT pullouts and fractures that enhance the service life of composites.
MIT Department
Massachusetts Institute of Technology. Department of Materials Science and Engineering
Terms of Use
Creative Commons Attribution-NonCommercial-NoDerivs License
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DOI of Published Version
https://doi.org/10.1016/j.carbon.2017.09.006
