Synthesis, Reactivity, and Electronic Properties of 6,6-Dicyanofulvenes
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Swager_Synthesis-with SI.pdf
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Author(s)
Swager, Timothy Manning
Andrew, Trisha Lionel
Cox, Jason R.
Date Issued
October 2010
Journal
Organic Letters
Publisher
American Chemical Society (ACS)
Citation
Andrew, Trisha L., Jason R. Cox, and Timothy M. Swager. “Synthesis, Reactivity, and Electronic Properties of 6,6-Dicyanofulvenes.” Organic Letters 12.22 (2010): 5302–5305.
Version
Author's final manuscript
Abstract
A series of 6,6-dicyanofulvene derivatives are synthesized starting from masked, dimeric, or monomeric cyclopentadienones. The reactivities of 6,6-dicyanofulvenes relative to their parent cyclopentadienones are discussed. 6,6-Dicyanofulvenes are capable of undergoing two consecutive, reversible, one-electron reductions and are presented as potential n-type small molecules.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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DOI of Published Version
https://doi.org/10.1021/ol102384k
