Angle-strained sila-cycloalkynes
Name
nihms-1987272.pdf
Description
Accepted version
Size
1.28 MB
Format
Adobe PDF
Checksum (MD5)
72121d55f5e84de825f0c85e5934a024
Author(s)
Wakefield, Herbert
Melvin, Sophia J
Jiang, Jennifer
Kevlishvili, Ilia
Siegler, Maxime A
Craig, Stephen L
Kulik, Heather J
Klausen, Rebekka S
Date Issued
April 5, 2024
Journal
Chemical Communications
Publisher
Royal Society of Chemistry
Citation
Wakefield, Herbert, Melvin, Sophia J, Jiang, Jennifer, Kevlishvili, Ilia, Siegler, Maxime A et al. 2024. "Angle-strained sila-cycloalkynes." Chemical Communications, 60 (36).
Version
Author's final manuscript
Abstract
Second row elements in small- and medium-rings modulate strain. Herein we report the synthesis of two novel oligosilyl-containing cycloalkynes that exhibit angle-strain, as observed by X-ray crystallography. However, the angle-strained sila-cyclooctynes are sluggish participants in cycloadditions with benzyl azide. A distortion-interaction model analysis based on density functional theory calculations was performed.
MIT Department
Massachusetts Institute of Technology. Department of Chemical Engineering
Massachusetts Institute of Technology. Department of Chemistry
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Creative Commons Attribution-Noncommercial-ShareAlike
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DOI of Published Version
https://doi.org/10.1039/d4cc00439f
