Palladium-Catalyzed Asymmetric Dearomatization of Naphthalene Derivatives
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Buchwald_Palladium-catalyzed.pdf
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Author(s)
Kessler, Florian
Garcia-Fortanet, Jorge
Buchwald, Stephen Leffler
Date Issued
April 2009
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Citation
García-Fortanet, Jorge, Florian Kessler, and Stephen L. Buchwald. “Palladium-Catalyzed Asymmetric Dearomatization of Naphthalene Derivatives.” Journal of the American Chemical Society 131, no. 19 (May 20, 2009): 6676-6677.
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Author's final manuscript
Abstract
An intramolecular enantioselective metal-catalyzed dearomatization reaction is described. This procedure allows the dearomatization of naphthalene derivatives through an electrophilic aromatic substitution-type reaction on a Pd(II) intermediate. The high yields and enantioselectivities achieved make this procedure a valuable method for synthetic chemists.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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DOI of Published Version
https://doi.org/10.1021/ja9025193
