The mechanics of strain-induced crystallization in poly(ethylene terephthalate)
Name
42192765-MIT.pdf
Description
Full printable version
Size
11.41 MB
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Checksum (MD5)
78bab48dd2303d03e6af697998466b22
Author(s)
Llana, Patricia G. (Patricia Gracia), 1974-
Advisor(s)
Mary C. Boyce.
Date Issued
1998
Publisher
Massachusetts Institute of Technology
Abstract
Poly( ethylene terephthalate) (PET) is a thermoplastic polymer found in numerous commercial applications. PET exhibits the capability of undergoing strain-induced crystallization during processing, the result of which is increased stiffness and hardness as well as better dimensional stability. An experimental study of the strain rate, strain state, and temperature dependencies of the stress-strain behavior of PET under large strain deformation was conducted over a wide range of strain rates (-0.005/s - 02.0/s) and temperatures (25 ° C - 105 ° C) and in both uniaxial and plane strain compression. The increase in crystallinity content with varying strain rate and temperature and for the two different states of strain that developed as a result of these deformation conditions was investigated using Differential Scanning Calorimetry (DSC). The nature and evolution of the crystallographic texture was studied using Wide Angle X-ray Diffraction (WAXD) measurements. The results of the mechanical tests, DSC and WAXD measurements indicated that straininduced crystallization does not occur in uniaxial compression at temperatures below the glass transition, however, a shift in the cold crystallization exotherm was observed. Alternatively, in plane strain compression at these temperatures for the fastest strain rates, DSC measurements indicated an increase in crystallinity. At temperatures near the glass transition in uniaxial compression, DSC measurements indicated an increase in crystallinity, whereas WAXD measurements indicated only molecular orientation. In plane strain compression, however, both DSC and WAXD measurements indicated an increase in crystallinity. At temperatures above the glass transition temperature, both DSC and WAXD indicated an increase in crystallinity in both uniaxial and plane strain compression. It was found that the percent crystallinity increased with increasing strain rate and decreasing temperature and that the crystallographic texture that develops is dependent on the state of strain. A constitutive model that predicts the strain rate, strain state and temperature dependence of PET was developed that captures these dependencies very well.
Description
Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 1998.
Includes bibliographical references (p. 279-282).
Subjects
Mechanical Engineering
MIT Department
Massachusetts Institute of Technology. Department of Mechanical Engineering
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