Reversible high-pressure carbon nanotube vessel
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Ma-2010-Reversible high-pres.pdf
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Author(s) • • • • • • • • •
Wang, Lifeng
Ma, Ming D.
Liu, Jefferson Z.
Shen, Luming
Xie, Lin
Wei, Fei
Zhu, Jing
Gong, Qianming
Liang, Ji
Zheng, Quanshui
Date Issued
June 2010
Journal
Physical Review B
Publisher
American Physical Society
Citation
Ma, Ming D. et al. “Reversible high-pressure carbon nanotube vessel.” Physical Review B 81.23 (2010): 235420. © 2010 The American Physical Society.
Version
Final published version
Abstract
Applying a full pressure loop, i.e., loading and unloading, on a nanocrystal with in situ observation remains a challenge to experimentalists up until now. Using a multiwalled carbon nanotube, we realize the pressure loop acting on a Fe3C nanocrystal (with peak value 20 GPa) by electron-beam irradiation with in situ observations inside transmission electron microscopy at 500 °C/ambient temperature. Using density-functional theory calculations, we attribute the unloading process to the formation of one dangling-bond single vacancies under the electron-beam irradiation at room temperature. A theoretical model is presented to understand the process and the results agree well with the experimental measurements.
MIT Department
Massachusetts Institute of Technology. Department of Mechanical Engineering
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1103/PhysRevB.81.235420