Synergistic Roll‐to‐Roll Transfer and Doping of CVD‐Graphene Using Parylene for Ambient‐Stable and Ultra‐Lightweight Photovoltaics
Name
10.1002-adfm.202001924.pdf
Size
1.24 MB
Format
Adobe PDF
Checksum (MD5)
7ddc3c10dc37cf3a4392ed421633b04d
Author(s)
Tavakoli, Mohammad Mahdi
Azzellino, Giovanni
Hempel, Marek
Lu, Ang‐Yu
Martin‐Martinez, Francisco J.
Zhao, Jiayuan
Yeo, Jingjie
Palacios, Tomas
Buehler, Markus J.
Kong, Jing
Date Issued
June 4, 2020
Journal
Advanced Functional Materials
Publisher
Wiley
Citation
Tavakoli, M. M., Azzellino, G., Hempel, M., Lu, A.-Y., Martin-Martinez, F. J., Zhao, J., Yeo, J., Palacios, T., Buehler, M. J., Kong, J., Synergistic Roll-to-Roll Transfer and Doping of CVD-Graphene Using Parylene for Ambient-Stable and Ultra-Lightweight Photovoltaics. Adv. Funct. Mater. 2020, 30, 2001924.
Version
Author's final manuscript
Abstract
A roll-to-roll (R2R) transfer technique is employed to improve the electrical properties of transferred graphene on flexible substrates using parylene as an interfacial layer. A layer of parylene is deposited on graphene/copper (Cu) foils grown by chemical vapor deposition and are laminated onto ethylene vinyl acetate (EVA)/poly(ethylene terephthalate). Then, the samples are delaminated from the Cu using an electrochemical transfer process, resulting in flexible and conductive substrates with sheet resistances of below 300 Ω sq−1, which is significantly better (fourfold) than the sample transferred by R2R without parylene (1200 Ω sq−1). The characterization results indicate that parylene C and D dope graphene due to the presence of chlorine atoms in their structure, resulting in higher carrier density and thus lower sheet resistance. Density functional theory calculations reveal that the binding energy between parylene and graphene is stronger than that of EVA and graphene, which may lead to less tear in graphene during the R2R transfer. Finally, organic solar cells are fabricated on the ultrathin and flexible parylene/graphene substrates and an ultra-lightweight device is achieved with a power conversion efficiency of 5.86%. Additionally, the device shows a high power per weight of 6.46 W g−1 with superior air stability.
MIT Department
Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
Massachusetts Institute of Technology. Laboratory for Atomistic and Molecular Mechanics
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DOI of Published Version
https://doi.org/10.1002/adfm.202001924
