High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework
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Author(s)
Narayan, Tarun Chandru
Miyakai, Tomoyo
Seki, Shu
Dinca, Mircea
Date Issued
August 2012
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society
Citation
Narayan, Tarun C., Tomoyo Miyakai, Shu Seki, and Mircea Dincă 2012 High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework. Journal of the American Chemical Society 134(31): 12932–12935.
Version
Author's final manuscript
Abstract
The tetratopic ligand tetrathiafulvalene-tetrabenzoate (H[subscript 4]TTFTB) is used to synthesize Zn[subscript 2](TTFTB), a new metal–organic framework that contains columnar stacks of tetrathiafulvalene and benzoate-lined infinite one-dimensional channels. The new MOF remains porous upon desolvation and exhibits charge mobility commensurate with some of the best organic semiconductors, confirmed by flash-photolysis-time-resolved microwave conductivity measurements. Zn[subscript 2](TTFTB) represents the first example of a permanently porous MOF with high charge mobility and may inspire further exploration of the electronic properties of these materials.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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DOI of Published Version
https://doi.org/10.1021/ja3059827
