Electrochemical Determination of the Thermodynamic Properties of Lithium-Antimony Alloys
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Sadoway_Electrochemical determination.pdf
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Author(s)
Kane, Margareet M.
Newhouse, Jocelyn M.
Sadoway, Donald Robert
Kane, Margaret M.
Date Issued
December 2014
Journal
Journal of the Electrochemical Society
Publisher
Electrochemical Society
Citation
Kane, M. M., J. M. Newhouse, and D. R. Sadoway. “Electrochemical Determination of the Thermodynamic Properties of Lithium-Antimony Alloys.” Journal of the Electrochemical Society 162, no. 3 (December 31, 2014): A421–A425.
Version
Final published version
Abstract
The variation in the high temperature thermodynamic properties of the Li-Sb system with temperature (425–775ºC) and composition (x[subscript Li] = 0.01–0.75) was determined by electromotive force (emf) measurements in a cell configured as follows: Li-Bi reference electrode (x[subscript Bi] = 0.35) | eutectic of LiCl-KCl or LiCl-LiF | Li-Sb alloy. On the basis of these data the Li-Sb couple was deemed attractive for storage of electrical energy in a liquid metal battery. In addition, an updated Li-Sb binary phase diagram is proposed.
MIT Department
Massachusetts Institute of Technology. Department of Materials Science and Engineering
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DOI of Published Version
https://doi.org/10.1149/2.0671503jes
