Pd-Catalyzed Synthesis of Ar-SCF3 Compounds under Mild Conditions
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Buchwald_Pd-catalyzed synthesis.pdf
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Author(s)
Teverovskiy, Georgiy
Surry, David S.
Buchwald, Stephen Leffler
Date Issued
June 2011
Journal
Angewandte Chemie International Edition
Publisher
Wiley Blackwell
Citation
Teverovskiy, Georgiy, David S. Surry, and Stephen L. Buchwald. “Pd-Catalyzed Synthesis of Ar-SCF3 Compounds under Mild Conditions.” Angewandte Chemie International Edition 50, no. 32 (August 1, 2011): 7312-7314.
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Author's final manuscript
Abstract
Good to excellent yields of aryl trifluoromethyl sulfides, which are an important class of compounds in both the pharmaceutical and agrochemical areas, can be achieved under mild conditions by the Pd-catalyzed reaction of aryl bromides with a trifluoromethylthiolate nucleophile (see scheme).
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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DOI of Published Version
https://doi.org/10.1002/anie.201102543
