Thermal Cycling of a MOF-Based NO Disproportionation Catalyst

Wright, Ashley M; Sun, Chenyue; Dincă, Mircea

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Thermal Cycling of a MOF-Based NO Disproportionation Catalyst

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Author(s)

Wright, Ashley M

•

Sun, Chenyue

•

Dincă, Mircea

Date Issued

2021

Journal

Journal of the American Chemical Society

Publisher

American Chemical Society (ACS)

Citation

Wright, Ashley M, Sun, Chenyue and Dincă, Mircea. 2021. "Thermal Cycling of a MOF-Based NO Disproportionation Catalyst." Journal of the American Chemical Society, 143 (2).

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Author's final manuscript

Abstract

© 2021 American Chemical Society. The metal-organic framework CuI-MFU-4l reacts with NO, initially forming a copper(I)-nitrosyl at low pressure, and subsequently generates NO disproportionation products CuII-NO2 and N2O. The thermal stability of MFU-4l allows NOx to be released from the framework at temperatures greater than 200 °C. This treatment regenerates the original CuI-MFU-4l, which can engage in subsequent cycles of NO disproportionation.

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https://hdl.handle.net/1721.1/141065

DOI of Published Version

10.1021/JACS.0C12134