Characterization of a synthetic peroxodiiron(III) protein model complex by nuclear resonance vibrational spectroscopy
Name
Do et al Chem Comm.pdf
Size
720.27 KB
Format
Adobe PDF
Checksum (MD5)
713c9fb1f7249ba2489f441b5bdbadf0
Author(s)
Do, Loi Hung
Wang, Hongxin
Tinberg, Christine E.
Dowty, Eric
Yoda, Yoshitaka
Cramer, Stephen P.
Lippard, Stephen J.
Date Issued
September 2011
Journal
Chemical Communications
Publisher
Royal Society of Chemistry, The
Citation
Do, Loi H. et al. “Characterization of a Synthetic Peroxodiiron(iii) Protein Model Complex by Nuclear Resonance Vibrational Spectroscopy.” Chemical Communications 47.39 (2011): 10945.
Version
Author's final manuscript
Abstract
The vibrational spectrum of an η[superscript 1],η[superscript 1]-1,2-peroxodiiron(III) complex was measured by nuclear resonance vibrational spectroscopy and fit using an empirical force field analysis. Isotopic 18O2 labelling studies revealed a feature involving motion of the {Fe2(O2)}[superscript 4+] core that was not previously observed by resonance Raman spectroscopy.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
Terms of Use
Creative Commons Attribution-Noncommercial-Share Alike 3.0
Persistent DSpace Link
DOI of Published Version
https://doi.org/10.1039/c1cc13836g
