Determining the concentration and source of lead in chocolate using lead isotopes
Name
1028749476-MIT.pdf
Description
Full printable version
Size
10.94 MB
Format
Adobe PDF
Checksum (MD5)
8fd11da7ef3767529dafe8907a263fbc
Author(s)
Thompson, Jessica Ann
Advisor(s)
Samuel Bowring.
Date Issued
2007
Publisher
Massachusetts Institute of Technology
Abstract
Single-origin dark chocolate samples derived from cocoa grown in developing countries from around the world were analyzed to determine their lead concentrations and the isotopic composition of the lead. The lead isotope ratios were compared with published data from aerosols and volcanic rocks nearest to the cocoa growing regions. Samples from different countries and manufacturers were compared, and we conclude that the source of lead depends on the country of origin and not the manufacturer. Chocolates grown in the Northern Hemisphere usually had lead isotope ratios that matched the global atmospheric lead isotopic signature from the Northern Hemisphere. Chocolates grown in the Southern Hemisphere did not match the global signature, but rather more closely matched the lead isotopic signature from volcanic rocks in their respective countries, and had a lower average lead concentration than chocolates from the Northern Hemisphere. Soils from Venezuela were also analyzed, and confirmed the conclusion that atmospheric lead is the predominant source of bioavailable lead. Many of the chocolates also had lead concentrations below the limit of 0.1 ppm set by the FDA; however, one manufacturer, Dagoba, consistently had lead concentrations above the limit. The percent of cocoa in each chocolate bar was also compared with the lead concentrations, concluding that the concentration of lead is not necessarily dependent on the amount of cocoa in the bar.
Description
Thesis: S.B., Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences, 2007.
Cataloged from PDF version of thesis. Pages 81 and 87 missing from original thesis.
Includes bibliographical references (pages 86-91).
Subjects
Earth, Atmospheric, and Planetary Sciences.
MIT Department
Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences
Terms of Use
MIT theses are protected by copyright. They may be viewed, downloaded, or printed from this source but further reproduction or distribution in any format is prohibited without written permission.
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