A microfabricated solid oxide fuel cell
Name
56795614-MIT.pdf
Description
Full printable version
Size
7.53 MB
Format
Adobe PDF
Checksum (MD5)
9ad9cc35775e5dc8022cc68887459316
Author(s)
Mehta, Ankur, 1983-
Advisor(s)
Martin A. Schmidt and Klavs F. Jensen.
Date Issued
2004
Publisher
Massachusetts Institute of Technology
Abstract
With the ever-increasing ubiquity of mobile consumer electronic devices comes the rising demand for portable electric power. Current battery technology gives a very modest energy return per weight or volume. Hydrocarbons have a significantly higher energy density, and so fuel conversion systems only need to have several percent efficiency to match and surpass the specific energy of conventional batteries. Thus, there is a strong market for successful portable fuel powered electric generators. The goal of this thesis is to investigate the design of one such device, a two-chamber microfabricated solid oxide fuel cell (SOFC). This device produces electric current through the electrochemical oxidation of fuel through an ionic conductor. Oxide ions permeate across a ceramic electrolyte membrane to react with the fuel, driving electrons back around through the load. The focus of this work is to analyze the behavior of these membranes to prevent failure as the device is heated to its operating temperature near 800K. Experiments and analysis of free-standing electrolyte membranes indicate that failure is unavoidable over the required temperature range, and so supported structures are investigated. The results of experiments with a perforated nitride supported membrane presented herein indicate the need for a more thorough understanding of the thin film stresses responsible for membrane failure, as well as careful support structures to accommodate these. Designs for future devices are presented to improve stability and move closer to a final complete portable power system.
Description
Thesis (M. Eng.)--Massachusetts Institute of Technology, Dept. of Electrical Engineering and Computer Science; and, (S.B.)--Massachusetts Institute of Technology, Dept. of Physics, 2004.
Includes bibliographical references (p. 83-85).
Subjects
Physics.
Electrical Engineering and Computer Science.
MIT Department
Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
Massachusetts Institute of Technology. Department of Physics
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