CH3-Terminated Carbon Chains in the GOTHAM Survey of TMC-1: Evidence of Interstellar CH3C7N
Name
Siebert_2022_ApJ_924_21.pdf
Description
Published version
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1.65 MB
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Author(s)
Siebert, Mark A
Lee, Kin Long Kelvin
Remijan, Anthony J
Burkhardt, Andrew M
Loomis, Ryan A
McCarthy, Michael C
McGuire, Brett A
Date Issued
January 1, 2022
Journal
The Astrophysical Journal
Publisher
American Astronomical Society
Citation
Siebert, Mark A, Lee, Kin Long Kelvin, Remijan, Anthony J, Burkhardt, Andrew M, Loomis, Ryan A et al. 2022. "CH3-Terminated Carbon Chains in the GOTHAM Survey of TMC-1: Evidence of Interstellar CH3C7N." The Astrophysical Journal, 924 (1).
Version
Final published version
Abstract
We report a systematic study of all known methyl carbon chains toward TMC-1 using the second data release of the GOTHAM survey, as well as a search for larger species. Using Markov Chain Monte Carlo simulations and spectral line stacking of over 30 rotational transitions, we report statistically significant emission from methylcyanotriacetylene (CH3C7N) at a confidence level of 4.6σ, and use it to derive a column density of ∼1011 cm−2. We also searched for the related species, methyltetraacetylene (CH3C8H), and place upper limits on the column density of this molecule. By carrying out the above statistical analyses for all other previously detected methyl-terminated carbon chains that have emission lines in our survey, we assess the abundances, excitation conditions, and formation chemistry of methylpolyynes (CH3C2nH) and methylcyanopolyynes (CH3C2n-1N) in TMC-1, and compare those with predictions from a chemical model. Based on our observed trends in column density and relative populations of the A and E nuclear spin isomers, we find that the methylpolyyne and methylcyanopolyyne families exhibit stark differences from one another, pointing to separate interstellar formation pathways, which is confirmed through gas–grain chemical modeling with nautilus.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Creative Commons Attribution 4.0 International license
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DOI of Published Version
https://doi.org/10.3847/1538-4357/ac3238
