Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion
Name
Swager_Fluorous-manuscript-check.pdf
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1.7 MB
Format
Adobe PDF
Checksum (MD5)
32a5056985e125a41e7b2a267800171e
Author(s)
Lim, Jeewoo
Swager, Timothy Manning
Date Issued
September 2010
Journal
Angewandte Chemie International Edition
Publisher
Wiley-VCH Verlag GmbH & Co. KGaA
Citation
Lim, J. and Swager, T. M. (2010), Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion. Angewandte Chemie International Edition, 49: 7486–7488. doi: 10.1002/anie.201003111
Version
Author's final manuscript
Abstract
It's just a phase: A highly fluorinated compound with a rigid three-dimensional architecture was synthesized as a monomer for poly(p-phenyleneethynylene)s (PPEs). Fluorous biphase reactions were applied for the synthesis of a PPE that is soluble only in fluorous solvents. A fluorous solution of the polymer could be processed into aqueous emulsions that display high fluorescence quantum yields (see picture).
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Creative Commons Attribution-Noncommercial-Share Alike 3.0
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DOI of Published Version
https://doi.org/10.1002/anie.201003111
