Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties
Name
ACS.CHEMMATER.9B02462.pdf
Description
Accepted version
Size
1.75 MB
Format
Adobe PDF
Checksum (MD5)
7bec97c73f62c10e3333a7d5ffe1369b
Author(s)
Cadiau, Amandine
Xie, Lilia S.
Kolobov, Nikita
Shkurenko, Aleksander
Qureshi, Muhammad
Tchalala, Mohamed R.
Park, Sarah Sunah
Bavykina, Anastasiya
Eddaoudi, Mohamed
Dinca, Mircea
Date Issued
December 2019
Journal
Chemistry of Materials
Publisher
American Chemical Society (ACS)
Citation
Cadiau, Amandine et al. "Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties." Chemistry of Materials 32, 1 (December 2019): 97–104 © 2019 American Chemical Society
Version
Author's final manuscript
Abstract
Nowadays, zirconium metal-organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. Herein, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV-vis spectroscopy. Their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
Terms of Use
Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
Persistent DSpace Link
DOI of Published Version
https://doi.org/10.1021/acs.chemmater.9b02462
