Carbanionic Route to Electroactive Carbon-Centered Anion and Radical Oligomers
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Swager_Carbanionic route with supporting doc.pdf
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8.35 MB
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Author(s)
Dane, Eric L.
Swager, Timothy Manning
Date Issued
September 2010
Journal
Organic Letters
Publisher
American Chemical Society
Citation
Dane, Eric L., and Timothy M. Swager. “Carbanionic Route to Electroactive Carbon-Centered Anion and Radical Oligomers.” Organic Letters 12 (2010): 4324-4327. Web. 15 Dec. 2011. © 2011 American Chemical Society
Version
Author's final manuscript
Abstract
The synthesis of poly-1,3-bisdiphenylene-2-phenyl allyl (BDPA) radicals via a new anionic oligomerization strategy is reported. The material displays a reversible reduction from the orange-red radical to the blue carbanion in solution.
Description
Experimental details and additional spectra are available free of charge via the Internet at http://pubs.acs.org.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1021/ol1017728
