Enhancing Performance Stability of Electrochemically Active Polymers by Vapor-Deposited Organic Networks
Name
10.1002-adfm.201706028.pdf
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1.91 MB
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bb591c04a439a716ee87e11ee045b79d
Author(s)
Mao, Xianwen
Liu, Andong
Tian, Wenda
Wang, Xiaoxue
Gleason, Karen K.
Hatton, T. Alan
Date Issued
January 8, 2018
Journal
Advanced Functional Materials
Publisher
Wiley
Citation
Mao, X., Liu, A., Tian, W., Wang, X., Gleason, K. K., Alan Hatton, T., Adv. Funct. Mater. 2018, 28, 1706028.
Version
Author's final manuscript
Abstract
Performance stability of electrochemically active polymers (EAPs) remains one of the greatest and long-standing challenges with regard to EAP-based technologies for a myriad of energy, biomedical, and environmental applications. The performance instability of EAPs originates from their structural alteration under repeated charge–discharge cycling and/or flexing. In this work, a conceptually new “soft confinement” strategy to enhance EAP performance stability, including cyclic and mechanical, by using rationally designed, vapor-deposited organic networks is presented. These chemically cross-linked networks, when in contact with an electrolyte solution, turn into ultrathin, elastic hydrogel coatings that encapsulate conformally the EAP micro-/nanostructures. Such hydrogel coatings allow easy passage of ions that intercalate with EAPs, while simultaneously mitigating the structural pulverization of the EAPs and/or their detachment from substrates. Fundamentally distinct from extensively studied “scaffolding” or “synthetic” approaches to stabilizing EAPs, this soft confinement strategy relies on a postmodification step completely decoupled from the EAP synthesis/fabrication, and enjoys the unique advantage of substrate-independency. Hence, this strategy is broadly applicable to various types of EAPs. The proposed stability enhancement strategy is demonstrated to be effective for a range of EAP systems with differing chemical and morphological characteristics under various testing conditions (repeated charging/discharging, bending, and twisting).
MIT Department
Massachusetts Institute of Technology. Department of Chemical Engineering
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DOI of Published Version
https://doi.org/10.1002/adfm.201706028
