Electrolyte selection for cobalt-free solid-state batteries
Name
1078147050-MIT.pdf
Description
Full printable version
Size
1.7 MB
Format
Adobe PDF
Checksum (MD5)
8d0740c8ee7e4fb58d20ca2218fa18c9
Author(s)
Hernandez Alvarez, Erick Ivan
Advisor(s)
Jennifer L. M. Rupp.
Date Issued
2018
Publisher
Massachusetts Institute of Technology
Abstract
Lithium-ion batteries are widespread in use due to their thermal stability and high energy density. The most common design uses an organic electrolyte and lithium-cobalt electrode. While safe under typical operating conditions, the use of an organic electrolyte subjects the battery user to certain risks; in particular, Li-ion liquid batteries are explosive when exposed to air and subject to thermal runoff, making them highly sensitive to any physical damage. The use of cobalt also poses a moral concern, as the mining and sourcing of cobalt is geographically restricted and most commonly sourced from countries that have a history of foreign exploitation and child labor. An all solid state battery is suggested as a possible alternative battery that reduces operation risks and maintains similar performance characteristics. Lithium-lanthanum-zirconium oxide is presented as a suitable electrolyte replacement. Coupled with cobalt-free electrodes, this battery design would provide a safer, more responsible battery.
Description
Thesis: S.B., Massachusetts Institute of Technology, Department of Materials Science and Engineering, 2018.
Cataloged from PDF version of thesis.
Includes bibliographical references (page 30).
Subjects
Materials Science and Engineering.
MIT Department
Massachusetts Institute of Technology. Department of Materials Science and Engineering
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