Universal Cyclic Topology in Polymer Networks
Name
PhysRevLett.116.188302.pdf
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562.53 KB
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Author(s)
Wang, Rui
Alexander-Katz, Alfredo
Johnson, Jeremiah A.
Olsen, Bradley D.
Date Issued
May 2016
Journal
Physical Review Letters
Publisher
American Physical Society
Citation
Wang, Rui, Alfredo Alexander-Katz, Jeremiah A. Johnson, and Bradley D. Olsen. "Universal Cyclic Topology in Polymer Networks." Phys. Rev. Lett. 116, 188302 (May 2016). © 2016 American Physical Society
Version
Final published version
Abstract
Polymer networks invariably possess topological defects: loops of different orders which have profound effects on network properties. Here, we demonstrate that all cyclic topologies are a universal function of a single dimensionless parameter characterizing the conditions for network formation. The theory is in excellent agreement with both experimental measurements of hydrogel loop fractions and Monte Carlo simulations without any fitting parameters. We demonstrate the superposition of the dilution effect and chain-length effect on loop formation. The one-to-one correspondence between the network topology and primary loop fraction demonstrates that the entire network topology is characterized by measurement of just primary loops, a single chain topological feature. Different cyclic defects cannot vary independently, in contrast to the intuition that the densities of all topological species are freely adjustable. Quantifying these defects facilitates studying the correlations between the topology and properties of polymer networks, providing a key step in overcoming an outstanding challenge in polymer physics.
MIT Department
Massachusetts Institute of Technology. Department of Chemical Engineering
Massachusetts Institute of Technology. Department of Chemistry
Massachusetts Institute of Technology. Department of Materials Science and Engineering
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1103/PhysRevLett.116.188302
