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Batson, Joel M., and Timothy M. Swager. “Poly( Para-Arylene)s via [2+2+2].” ACS Macro Letters, 1, 9 (September 2012): 1121–23.
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Author's final manuscript
Abstract
We report a versatile new synthetic route to poly(para-phenylene)s (PPPs) and related poly(para-arylene)s containing high degrees of substitution not readily available by other methods. Our method transforms highly soluble, alkyne-containing polymers into PPPs via high-yielding, transition metal-mediated [2+2+2] cyclizations.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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