Analysis of Thermal Diodes Enabled by Junctions of Phase Change Materials
Name
Thermal Diode Phase Change.pdf
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937.59 KB
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Adobe PDF
Checksum (MD5)
2e0ebf68f1f86cb8e54c7ca2511b26d8
Author(s)
Strano, Michael S.
Cottrill, Anton Lee
Date Issued
September 2015
Journal
Advanced Energy Materials
Publisher
Wiley Blackwell
Citation
Cottrill, Anton L., and Michael S. Strano. “Analysis of Thermal Diodes Enabled by Junctions of Phase Change Materials.” Adv. Energy Mater. 5, no. 23 (September 10, 2015): n/a–n/a.
Version
Author's final manuscript
Abstract
Materials designed to undergo a phase transition at a prescribed temperature have been advanced as elements for controlling thermal flux. Such phase change materials can be used as components of reversible thermal diodes, or materials that favor heat flux in a preferred direction; however, a thorough mathematical analysis of such diodes is thus far absent from the literature. Herein, it is shown mathematically that the interface of a phase change material with a phase invariant one can function as a simple thermal diode. Design equations are derived for such phase change diodes, solving for the limits where the transition temperature falls within or outside of the temperature gradient across the device. Criteria are derived analytically for the choice of thermal conductivity of the invariant phase to maximize the rectification ratio. Finally, the model is applied to several experimental systems in the literature, providing bounds on observed performance. This model should aid in the development of materials capable of controlling heat flux.
MIT Department
Massachusetts Institute of Technology. Department of Chemical Engineering
Terms of Use
Creative Commons Attribution-Noncommercial-Share Alike
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DOI of Published Version
https://doi.org/10.1002/aenm.201500921
