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Nanostructure and Nanomechanics of Cement: Polydisperse Colloidal Packing

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Author(s)
Masoero, Enrico
•
Del Gado, E.
•
Pellenq, Roland Jm
•
Ulm, Franz-Josef
•
Yip, Sidney
Date Issued
October 2012
Journal
Physical Review Letters
Publisher
American Physical Society
Citation
Masoero, E. et al. “Nanostructure and Nanomechanics of Cement: Polydisperse Colloidal Packing.” Physical Review Letters 109.15 (2012):[4 pages]. Web. © 2012 American Physical Society.
Version
Final published version
Abstract
Cement setting and cohesion are governed by the precipitation and growth of calcium-silicate-hydrate, through a complex evolution of microstructure. A colloidal model to describe nucleation, packing, and rigidity of calcium-silicate-hydrate aggregates is proposed. Polydispersity and particle size dependent cohesion strength combine to produce a spectrum of packing fractions and of corresponding elastic properties that can be tested against nanoindentation experiments. Implications regarding plastic deformations and reconciling current structural characterizations are discussed.
MIT Department
Massachusetts Institute of Technology. Department of Civil and Environmental Engineering
Massachusetts Institute of Technology. Department of Nuclear Science and Engineering
Terms of Use
Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
Persistent DSpace Link
http://hdl.handle.net/1721.1/76305
DOI of Published Version
https://doi.org/10.1103/PhysRevLett.109.155503
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