Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies
Name
s1-ln109186195844769-1939656818Hwf-895351682IdV-2166532551091861PDF_HI0001.pdf
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3.2 MB
Format
Adobe PDF
Checksum (MD5)
3fd12c73d0185d039621d26a93805163
Author(s)
VanVeller, Brett
Swager, Timothy Manning
Schipper, Derek James
Date Issued
April 2012
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society
Citation
VanVeller, Brett, Derek J. Schipper, and Timothy M. Swager. “Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies.” Journal of the American Chemical Society 134.17 (2012): 7282–7285. CrossRef. Web.
Version
Author's final manuscript
Abstract
The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold enforces proximity of the alcohol and arene reacting partners and confers significant rigidity to the resulting π-system, expanding the tool set of iptycenes for materials applications.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
Terms of Use
Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1021/ja3018253
